Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex.
نویسندگان
چکیده
The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr'(2) (1) and Ar'CoN(SiMe(3))(2) (2) (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-(i)Pr(2))(2)) are reported. The magnetic data for 2 show that it has an unexpectedly high mu(eff) of 5.65 mu(B) whereas the bent complex 1 has a significantly lower moment.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 25 شماره
صفحات -
تاریخ انتشار 2010